Excellent sustained-release efficacy of herbicide quinclorac with cationic covalent organic frameworks
文献类型: 外文期刊
作者: Deng, Xile 1 ; Zhao, Pengyue 2 ; Zhou, Xiaomao 1 ; Bai, Lianyang 1 ;
作者机构: 1.Hunan Acad Agr Sci, Hunan Agr Biotechnol Res Inst, State Key Lab Hybird Rice, Key Lab Biol & Control Weeds, 2 Yuanda Rd, Changsha 410125, Peoples R China
2.Chinese Acad Agr Sci, Inst Plant Protect, Key Lab Integrated Pest Management Crops, Minist Agr, 2 Yuanmingyuan West Rd, Beijing 100193, Peoples R China
关键词: Covalent organic frameworks; Control release; Nanosheets; Quinclorac; Barnyard grass
期刊名称:CHEMICAL ENGINEERING JOURNAL ( 影响因子:13.273; 五年影响因子:11.529 )
ISSN: 1385-8947
年卷期: 2021 年 405 卷
页码:
收录情况: SCI
摘要: Ethidium bromide-based covalent organic frameworks (EB-COFs) possess excellent stability and strong adsorption capacities due to their rich cationic charge in the porous structures, making them potential drug release carriers. In this research, EB-COFs nanosheets were prepared for loading and controlling the release of quinclorac (QNC) by mechanical delamination. The loading capacity of QNC into EB-COFs was determined as 41% (w/w). Compared to QNC technical concentrate (TC), the as-obtained stimuli-responsive nanosheets displayed prior controlled-release characteristics. Furthermore, QNC-loaded EB-COFs nanosheets displayed excellent herbicide activities against barnyard grass (Echinochloa crusgalli), when compared to QNC TC. In sum, herbicidal COFs nanosheets look potential as a novel efficient delivery system for pesticide formulations.
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