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Dissipation Dynamic and Final Residues of Oxadiargyl in Paddy Fields Using High-Performance Liquid Chromatography-Tandem Mass Spectrometry Coupled with Modified QuEChERS Method

文献类型： 外文期刊

作者： Deng, Xile 1 ; Zhou, Yong 1 ; Zheng, Wenna 1 ; Bai, Lianyang 1 ; Zhou, Xiaomao 1 ;

作者机构： 1.Hunan Acad Agr Sci, Hunan Agr Biotechnol Res Inst, Changsha 410125, Hunan, Peoples R China

2.Hunan Univ, Long Ping Branch, Grad Sch, Changsha 410125, Hunan, Peoples R China

关键词： herbicide; degradation; residues; rice; HPLC; MS-MS

期刊名称：INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH （ 影响因子：3.39； 五年影响因子：3.789 ）

ISSN： 1660-4601

年卷期： 2018 年 15 卷 8 期

页码：

收录情况： SCI

摘要： Oxadiargyl, which binds to the protoporphyrinogen oxidase IX to exhibit herbicide activity, is mainly used in the prevention of certain perennial broadleaved and grass weeds during the preemergence of rice in paddy fields. However, oxadiargyl affects the germination and seedling growth of rice, causing damage to the plant and reducing rice yield. Hence, monitoring fate and behaviour of oxadiargyl in rice paddy fields is of great significance. A modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) sample preparation method coupled with high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was established in paddy water, paddy soil, rice straw, paddy hull, and brown rice. We validated this method for the first time in the analysis of the dissipation dynamic and residues of oxadiargyl over two years (2015-2016) at three sites in China. The average recoveries of oxadiargyl ranged from 76.0 to 98.8%, with relative standard deviations of 3.5-14.0%. The dissipation curves for paddy soil fit to a first-order kinetic equation, revealing that oxadiargyl degraded rapidly in paddy soil with half-lives (t(1/2)) of 4.5-7.6 days. The final oxadiargyl residues in all samples remained below the detection limit and the maximum residue limit in China (0.02 mg kg(-1)) and Japan (0.05 mg kg(-1)) during the harvesting dates and were not detected in rice straw.

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