文献类型： 外文期刊

作者： Han, Er-Meng ¹ ; Yu, Wei-Dong ² ; Li, Lei-Jiao ³ ; Yi, Xiao-Yi ¹ ; Yan, Jun ¹ ; Liu, Chao ¹ ;

作者机构： 1.Cent South Univ, Hunan Prov Key Lab Chem Power Sources, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

2.Hunan Acad Agr Sci, Hunan Inst Nucl Agr Sci & Space Breeding, Changsha 410000, Peoples R China

3.Changchun Univ Sci & Technol, Jilin Prov Sci & Technol Innovat Canter Optic Mat, Sch Chem & Environm Engn, Changchun 130022, Jilin, Peoples R China

期刊名称：CHEMICAL COMMUNICATIONS （ 影响因子：5.996； 五年影响因子：5.818 ）

ISSN： 1359-7345

年卷期： 2021 年 57 卷 22 期

页码：

收录情况： SCI

摘要： We report here the synthesis of a ferrocene-functionalized {Ti(22)Fc(4)} cluster with a 'dimer-of-clusters' topology, which represents the largest Ti-oxo cluster (TOC) modified with organometallic groups ever reported. The exact assembly path of {Ti(22)Fc(4)} can be inferred from its two substructures, {Ti(11)Fc(2)} and {Ti(5)Fc}, which can also be synthesized independently through subtle changes in reaction conditions. Furthermore, we used these clusters as photocatalysts, and have studied, for the first time, the photocatalytic activity of TOCs in the oxidative coupling of amines.