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Monocarboxylate-driven structural growth in Calix[n]arene-polyoxotitanate hybrid systems: utility in hydrogen production from water

文献类型: 外文期刊

作者: Yang, Xin-Xue 1 ; Yu, Wei-Dong 2 ; Yi, Xiao-Yi 1 ; Li, Lei-Jiao 3 ; Liu, Chao 1 ;

作者机构: 1.Cent South Univ, Hunan Prov Key Lab Chem Power Sources, Coll Chem & Chem Engn, Changsha 410083, Peoples R China

2.Hunan Acad Agr Sci, Hunan Inst Nucl Agr Sci & Space Breeding, Changsha 410000, Peoples R China

3.Changchun Univ Sci & Technol, Jilin Prov Sci & Technol Innovat Canter Opt Mat &, Sch Chem & Environm Engn, Changchun 130022, Jilin, Peoples R China

期刊名称:CHEMICAL COMMUNICATIONS ( 影响因子:6.222; 五年影响因子:6.008 )

ISSN: 1359-7345

年卷期: 2020 年 56 卷 90 期

页码:

收录情况: SCI

摘要: A carboxylate-driven assembly strategy has been developed for the first time to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that these clusters exhibit structural-dependent H-2 evolution ability with a maximum rate up to 415.11 mu mol h(-1) g(-1), which is almost the highest recorded in polyoxotitanate clusters.

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