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Self-Assembled Sphere Covalent Organic Framework with Enhanced Herbicidal Activity by Loading Cyhalofop-butyl

文献类型： 外文期刊

作者： Deng, Xile 1 ; Zhao, Pengyue 2 ; Xie, Yong 3 ; Bai, Lianyang 1 ;

作者机构： 1.Hunan Acad Agr Sci, Hunan Agr Biotechnol Res Inst, Changsha 410125, Hunan, Peoples R China

2.Chinese Acad Agr Sci, Inst Plant Protect, Key Lab Integrated Pest Management Crops, Minist Agr, Beijing 100193, Peoples R China

3.China Agr Univ, Coll Sci, Dept Appl Chem, Beijing 100193, Peoples R China

关键词： covalent organic framework; nanopesticide; high loads; enhanced bioactivity; sustainable agriculture

期刊名称：JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY （ 影响因子：6.1； 五年影响因子：6.3 ）

ISSN： 0021-8561

年卷期： 2023 年

页码：

收录情况： SCI

摘要： Nanopesticides are considered to be a novel and efficient kind of tool for controlling pests in modern agriculture. Covalent organic frameworks (COFs), with high surface areas, ordered structures, and rich functional groups for loading pesticides, are a class of promising carrier materials that can be used to develop efficient nanopesticide delivery systems. However, until now, only a strong ionic interaction between the pesticide and COF can be utilized to achieve the combination between the pesticide and COF. On the basis of this method, charged pesticide molecules are the only choice for COF-based nanopesticides, which limits the exploitation. The way to load the uncharged pesticide molecules into COF still needs to be explored. Herein, in this research, we provided a commonly mild and high-efficacy strategy for loading an uncharged pesticide molecule into COF. The herbicide cyhalofop-butyl (CB), as a neutral model pesticide molecule, was loaded into the sphere COF (SCOF, a model COF synthesized at room temperature) without any ionic interaction via the host-guest strategy. The loading capacity of CB into SCOF (CB@SCOF) was determined at 57% (w/w). Smaller CB@SCOF particles (150-200 nm) can efficiently enter the weed leaves and stems, enhancing the accumulation of the effective concentration in weeds, thus increasing herbicidal activity, in comparison to CB emulsifiable (EC, micrometer scale). Furthermore, CB@SCOF had a solubilization effect for CB in water and can improve the photostability of CB. Thus, the CB-loaded COF nanosphere showed excellent herbicidal activities against the target weeds Echinochloa crus-galli and Leptochloa chinensis compared to commercial CB EC. In conclusion, this study also provides a mild and high-efficacy pesticide loading strategy for COFs. The constructed efficient delivery system and pesticide formulation containing herbicidal COF nanospheres exhibit great potential applications for controlling weeds in sustainable agriculture.

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[1]Self-Assembled Sphere Covalent Organic Framework with Enhanced Herbicidal Activity by Loading Cyhalofop-butyl. Deng, Xile,Zhao, Pengyue,Xie, Yong,Bai, Lianyang. 2023

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