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Synthesis of Cellulose-2,3-bis(3,5-dimethylphenylcarbamate) in an Ionic Liquid and Its Chiral Separation Efficiency as Stationary Phase

文献类型： 外文期刊

作者： Liu, Runqiang 2 ; Zhang, Yijun 2 ; Bai, Lianyang 1 ; Huang, Mingxian 2 ; Chen, Jun 2 ; Zhang, Yuping 2 ;

作者机构： 1.Hunan Agr Univ, Coll Plant Protect, Changsha 410128, Hunan, Peoples R China

2.Henan Inst Sci & Technol, Coll Chem & Chem Engn, Xinxiang 453003, Peoples R China

3.Hunan Acad Agr Sci, Changsha 410125, Hunan, Peoples R China

关键词： 1-allyl-3-methyl-imidazolium chloride;synthesis;Cellulose-2,3-bis(3,5-dimethylphenylcarbamate);high performance liquid chromatography;chiral stationary phase;enantioseparation

期刊名称：INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES （ 影响因子：5.923； 五年影响因子：6.132 ）

ISSN： 1422-0067

年卷期： 2014 年 15 卷 4 期

页码：

收录情况： SCI

摘要： A chiral selector of cellulose-2,3-bis(3,5-dimethylphenylcarbamate) (CBDMPC) was synthesized by reacting 3,5-dimethylphenyl isocyanate with microcrystalline cellulose dissolved in an ionic liquid of 1-allyl-3-methyl-imidazolium chloride (AMIMCl). The obtained chiral selector was effectively characterized by infrared spectroscopy, elemental analysis and 1H NMR. The selector was reacted with 3-aminopropylsilanized silica gel and the CBDMPC bonded chiral stationary phase (CSP) was obtained. Chromatographic evaluation of the prepared CSPs was conducted by high performance liquid chromatographic (HPLC) and baseline separation of three typical fungicides including hexaconazole, metalaxyl and myclobutanil was achieved using n-hexane/ isopropanol as the mobile phase with a flow rate 1.0 mL/min. Experimental results also showed that AMIMCl could be recycled easily and reused in the preparation of CSPs as an effective reaction media.

  • 相关文献

[1]Green synthesis of a typical chiral stationary phase of cellulose-tris(3,5-dimethylphenylcarbamate). Bai, Lian-yang,Liu, Run-Qiang,Zhang, Yi-Jun,Zhang, Yu-Ping,Bai, Lian-yang. 2013

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