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Abiotic transformation of atrazine in aqueous phase by biogenic bixbyite-type Mn2O3 produced by a soil-derived Mn(II)-oxidizing bacterium of Providencia sp.

文献类型： 外文期刊

作者： Luo, Jun 1 ; Ruan, Xiaofang 1 ; Chen, Wuying 2 ; Chen, Sha 1 ; Ding, Zhexu 3 ; Chen, Ang 2 ; Li, Ding 1 ;

作者机构： 1.Hunan Univ Technol, Sch Life Sci & Chem, Zhuzhou 412007, Peoples R China

2.Hunan Plant Protect Inst, Hunan Acad Agr Sci, Changsha 410125, Peoples R China

3.Nanjing Agr Univ, Jiangsu Prov Key Lab Organ Solid Waste Utilizat, Nanjing 210095, Peoples R China

4.Hunan Univ Technol, Hunan Prov Engn Res Ctr Lily Germplasm Resource In, Zhuzhou 412007, Peoples R China

关键词： Atrazine; Biogenic bixbyite-type Mn2O3; Degradation; Mn(II)-oxidizing bacterium; Providencia sp.

期刊名称：JOURNAL OF HAZARDOUS MATERIALS （ 影响因子：14.224； 五年影响因子：12.984 ）

ISSN： 0304-3894

年卷期： 2022 年 436 卷

页码：

收录情况： SCI

摘要： Recently, biogenic Mn oxides (BioMnO(x)) are considered as the promising degradation agents for environmental organic contaminants. However, little information is available for the degradation of atrazine by BioMnO(x). In this work, BioMnO(x), generated by a soil-derived Mn(II)-oxidizing bacterium, Providencia sp. LLDRA6, was explored to degrade atrazine. To begin with, collective results from mineral characterization analyses demonstrated that this BioMnO(x) was biogenic bixbyite-type Mn2O3. After that, purified biogenic Mn2O3 was found to exhibit a much higher removal efficiency for atrazine in aqueous phase, as compared to unpurified biogenic Mn2O3 and LLDRA6 biomass. During the atrazine removal by biogenic Mn2O3, six intermediate degradation products were discovered, comprising deethylatrazine (DEA), hydroxylatrazine (HA), deethylhydroxyatrazine (DEHA), ammeline, cyanuric acid, and 5-methylhexahydro-1,3,5-triazine-2-thione (MTT). Particularly, the intermediate, MTT, was considered as a new degradation product of atrazine, which was not described previously. Meanwhile, Mn(II) ions were released from biogenic Mn2O3, and on the surface of biogenic Mn2O3, the content of hydroxyl O species increased at the expense of that of lattice and water O species, but the fundamental crystalline structure of this Mn oxide remained unchanged. Additionally, no dissociative Mn(III) was found to involve in atrazine degradation. In summary, these results demonstrated that both the non-oxidative and oxidative reactions underlay the degradation of atrazine by biogenic Mn2O3.

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