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Comparison of properties, adsorption performance and mechanisms to Cd(II) on lignin-derived biochars under different pyrolysis temperatures by microwave heating

文献类型： 外文期刊

作者： Wu, Fangfang 1 ; Chen, Long 1 ; Hu, Peng 1 ; Zhou, Xia 1 ; Zhou, Huoqiang 2 ; Wang, Duanhua 2 ; Lu, Xiangyang 1 ; Mi, Baobin 1 ;

作者机构： 1.Hunan Agr Univ, Coll Biosci & Biotechnol, Coll Agron, Sch Chem & Mat Sci, Changsha 410128, Hunan, Peoples R China

2.Hunan Acad Agr Sci, Res Inst Vegetables, Changsha 410125, Peoples R China

关键词： Lignin; Biochar; Microwave heating; Cd(II) removal; Adsorption mechanism

期刊名称：ENVIRONMENTAL TECHNOLOGY & INNOVATION （ 影响因子：7.758； 五年影响因子：7.375 ）

ISSN： 2352-1864

年卷期： 2022 年 25 卷

页码：

收录情况： SCI

摘要： The application of biochar derived from various biomass to treat heavy metal pollution has received particular attention in recent years. Lignin is an abundant, highly aromatic byproduct from the paper-making industry with a low utilization rate, which is a potential feedstock for biochar preparation. In this study, lignin was carbonized at different temperatures by microwave heating to obtain biochars (LBx), and the effect of pyrolysis temperature on biochar properties, Cd(II) adsorption behavior, and mechanisms was comprehensively investigated. It was found that the biochar-inherent minerals gradually enriched, the surface functional groups decomposed, and more structural defects formed at the edges of graphite-like structures with the increasing pyrolysis temperature. Adsorption experiments demonstrated that the adsorption capacity of lignin improved significantly after carbonization. And as the temperature increased from 200 degrees C to 500 degrees C, the q(m) of LBx increased from 573.27 to 635.44 mg.g(-1), which were vastly superior to common reported biochars. The adsorption mechanisms of Cd(II) on the LBx can be classified into the interaction with dissolved fractions (biochar-inherent minerals co-precipitation and DOM interaction) and bulk biochar (surface complexation and ionic exchange). The quantitative mechanisms indicated that the dissolved matters contribute more to Cd(II) adsorption than bulk biochar, but the contribution decreased from 89.48% to 77.38% with increasing temperature. Surface complexation and ionic exchange are two dominant mechanisms on bulk biochar, and the former has a more significant advantage for higher-temperature prepared biochar. Taken together, lignin was an efficient and promising feedstock to prepare biochar used for Cd(II) removal. (C) 2021 The Author( s ). Published by Elsevier B.V.

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